The heteroleptic magnesium alkyl complex [CH{C(Me)NAr}(2)Mg(n)Bu] (Ar = 2,6-(i)Pr(2)C(6)H(3)) is reported as a highly efficient pre-catalyst for the hydroboration of aldehydes and ketones with pinacolborane.
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Arrowsmith et al. (2012) studied this question.
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