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Evaluate state-of-the-art catalyst systems, reaction mechanisms, and technical implementations in industrial alkene hydroformylation.

August 31, 2012Chemical Reviews

Applied Hydroformylation

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Evaluate state-of-the-art catalyst systems, reaction mechanisms, and technical implementations in industrial alkene hydroformylation.
Survey of rhodium- and cobalt-catalyzed hydroformylation processes spanning homogeneous and biphasic reaction systems.
Analysis of ligand architecture effects, including phosphines, phosphites, and chelating diphosphites, on catalytic activity and regioselectivity.
Assessment of industrial catalyst recovery, recycling technologies, and reaction engineering strategies across commercial plants.
Rhodium-bisphosphite complexes achieve exceptionally high linear-to-branched regioselectivities exceeding 95:1 for lower and higher olefins.
Two-phase aqueous catalytic systems enable efficient catalyst immobilization and separation, minimizing noble metal loss in commercial oxo processes.

Authors

RFRobert FrankeEvonik (Germany)DSDetlef SelentLeibniz Institute for Catalysis ABArmin BörnerUniversité Paris-Sud

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Implication

Review synthesizes industrial catalyst technologies and reaction engineering in alkene hydroformylation, highlighting strategies to optimize aldehyde selectivity and catalyst longevity.

Cite This Study

Franke et al. (2012) studied this question.

synapsesocial.com/papers/69dd87bb26032fe00d1013ad https://doi.org/10.1021/cr3001803

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Implication

Review synthesizes industrial catalyst technologies and reaction engineering in alkene hydroformylation, highlighting strategies to optimize aldehyde selectivity and catalyst longevity.

Applied Hydroformylation

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Discussion

Implication

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Applied Hydroformylation

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Discussion

Implication

Cite This Study

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