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A large H2 sorption capacity and high surface area are properties of the depicted metal–organic porous material, which is easily synthesized on a large scale from readily available chemicals. The rigid framework of Zn2(1,4-bdc)2(dabco) (1,4-H2bdc=1,4-benzenedicarboxylic acid; dabco=diazabicyclo2.2.2octane) is also flexible enough to exhibit unusual guest-dependent dynamic behavior, as shown (DMF=N,N-dimethylformamide).
Dybtsev et al. (Wed,) studied this question.
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