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Hydrosilylation reactions of 1-hexene and ethylene with SiH4 occurs in the presence of LiAlH4 as a catalyst. Hexylsilane and dihexylsilane were produced from 1-hexene and SiH4. Ethylsilane was produced from ethylene and SiH4. The reaction mechanism involving SiH4 and the alkyl anion, which is formed by the interaction between LiAlH4 and the olefin, has been proposed.
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Kobayashi et al. (1996) studied this question.
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