Deep Red Photocatalysis via Direct S 0 →T 1 Excitation of an Ir(III) Complex using 740 nm Light

Key Points

• To investigate deep-red photochemistry of an Ir(III) complex using 740 nm light.
• Examined photochemical reactions of an Ir(III) complex
• Used 740 nm light to achieve direct excitation
• Analyzed triplet state manifold populations
• Identified successful deep-red Ir(III) photochemistry
• Demonstrated long-lived triplet state from direct excitation
• Provided first examples of deep-red photocatalysis using this system