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April 19, 2026Angewandte ChemieOpen Access

Self‐Limiting Polymerization‐Induced Crystallization‐Driven Self‐Assembly (SL‐PI‐CDSA) Enables Templated Synthesis of Chiral Plasmonic, Hybrid 2D Hexagonal Assemblies

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Authors

RSRandall A. ScangaSSSean H. SaraultAKAmin Kiani

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Overview

Demonstrates templated synthesis of chiral plasmonic materials using self-limiting assembly.

Key Points

  • This research aims to explore a novel method for creating chiral hybrid nanomaterials through self-assembly.
  • Utilized self-limiting polymerization-induced crystallization-driven self-assembly (SL-PI-CDSA).
  • Created size-tunable 2D hexagonal nanosheets from aryl isocyanide (AIC) monomers.
  • Examined structural characteristics and topological defects of the nanosheets.
  • Achieved rapid assembly (≤ 5 minutes) with ultralow dispersity (Ð ≤ 1.01).
  • Fabricated functional chiral hybrid organic-inorganic nanomaterials incorporating chiral plasmonic metal nanoparticles.
  • Induced symmetry breaking in gold nanoparticles through template-driven confinement.

Cite This Study

Scanga et al. (2026) studied this question.

synapsesocial.com/papers/69e472a8010ef96374d8e96dhttps://doi.org/10.1002/ange.7896560
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  1. 1Self‐Limiting Polymerization‐Induced Crystallization‐Driven Self‐Assembly (SL‐PI‐CDSA) Enables Templated Synthesis of Chiral Plasmonic, Hybrid 2D Hexagonal Assemblies2026 · 1 citations
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  4. 4Polymerization‐induced Chiral Self‐assembly for the In situ Construction, Modulation, Amplification and Applications of Asymmetric Suprastructures2024
  5. 5Geometry‐Controlled Assembly of Self‐Standing Nanorods With Undisturbed Plasmonics2026