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Potentiometric analysis shows complex formation and stability constants of b-diketone with Ni(II) and Co(II), suggesting implications for coordination chemistry.
The study of stability constant of b-diketone 1-(4-methylthiophen-2-yl)-3-(2,4dihydroxyphenyl) -propane 1,3 dione[L4] with metal ion form complex with Ni(II) and Co (II) have been studied at 0.1 M ionic Strength at RT. Potentiometricaly in aqueous media by titrating with standard NaOH solution. The complexes formation between Ni(II) and Co (II) metal ions Hence it is observed that Nickel, Cobalt metal ions formed 1:1 and 1:2 complexes with b-diketone ligands (L). The observed values were comparing with the values of pH and metal-ligand stability constants and dissociate constant.
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Ashok N. Nagargoje (2026) studied this question.
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