Demonstrates regioselective hydroarylation in indole-ynones, suggesting a pathway to carbazole derivatives.
A gold(I)-catalyzed regioselective umpolung hydroarylation of indole-ynones to dihydrocarbazoles is reported. When a vinyl group is installed at the carbonyl end, ynone umpolung arylation is achieved, followed by tandem Nazarov...
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Ye et al. (2025) studied this question.
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