Demonstrates effective thiocyanosulfonylation of allenes, indicating its synthetic application potential.
A three-component thiocyanosulfonylation of allenes via copper catalysis is described, affording a variety of SCN-containing vinyl sulfones with excellent chemo-, regio-, and stereoselectivity under mild conditions. This protocol exhibits wide functional group tolerance and good broad compatibility with various allenes and sulfonyl chlorides, and shows potential for applications in synthetic chemistry.
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Guo et al. (2026) studied this question.
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