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April 22, 2026Zeitschrift für Kristallographie - New Crystal StructuresOpen Access

Crystal structure of (chloromethyl)triphenylphosphonium tetrachlorido-cobaltate(II), C ₃₈ H ₃₄ Cl ₆ CoP ₂

Yuanci Li Qiong Wu Hongjuan Tong Bin Liu Wenqiang Tang

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Key Points

The aim is to determine the crystal structure of chloromethyltriphenylphosphonium tetrachlorido-cobaltate(II).
Utilized single-crystal X-ray diffraction to analyze the molecular structure.
Measured parameters included a = 12.3921(5) Å, b = 15.5733(6) Å, c = 20.2150(7) Å, and β = 96.037(2)°.
Characterized the structure under standard temperature conditions (T = 293 K).
The structure was determined to be monoclinic with space group P2₁/n, indicating distinct molecular arrangement.
The volume (V) of the unit cell was found to be 3879.6(3) Å³.
Refinement results included R gt (F) = 0.0505 and wR ref (F²) = 0.1182.

Implication

The study demonstrates the crystal structure of cobaltate(II) in a monoclinic form, highlighting its molecular arrangement.

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Cite This Study

Li et al. (2026) studied this question.

synapsesocial.com/papers/69f04e5b727298f751e7254f https://doi.org/10.1515/ncrs-2026-0072

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