Crystal structure of bis(cyanomethyl-triphenylphosphonium) tetrachloridocobaltate(II), C 40 H 34 Cl 4 CoN 2 P 2

Q: What does this research mean for the field?

The crystal structure of bis(cyanomethyl-triphenylphosphonium) tetrachloridocobaltate(II) is monoclinic, space group P21/c, with a = 12.2511(3) Å, b = 15.6453(3) Å, c = 20.0571(4) Å, and β = 96.2500(10)°. Novelty: ClaimNovelty.NOVEL_FINDING. Consensus alignment: ConsensusAlignment.NEUTRAL.

Q. Wang; Mo Du; Xiaolin Dang; Xiaona Xu; Bin Liu

doi:10.1515/ncrs-2026-0305

August 19, 2026Zeitschrift für Kristallographie - New Crystal StructuresOpen Access

Crystal structure of bis(cyanomethyl-triphenylphosphonium) tetrachloridocobaltate(II), C 40 H 34 Cl 4 CoN 2 P 2

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Key Points

Determine the precise single-crystal structure and unit-cell parameters of the coordination complex bis(cyanomethyl-triphenylphosphonium) tetrachloridocobaltate(II).
Conducted single-crystal X-ray diffraction analysis at a data collection temperature of T = 150.00 K.
Determined and refined crystallographic lattice parameters, space group symmetry, and atomic positions.
The compound crystallizes in the monoclinic space group P21/c (no. 14) with unit cell dimensions a = 12.2511(3) Å, b = 15.6453(3) Å, c = 20.0571(4) Å, and β = 96.2500(10)°.
The crystal lattice exhibits a cell volume of V = 3821.54(14) Å³ with Z = 4 formula units per unit cell.
Structure refinement converged with reliability factors of Rgt(F) = 0.0222 and wRref(F²) = 0.0580.

Implication

Crystallographic analysis reveals the monoclinic crystal structure and unit cell parameters of bis(cyanomethyl-triphenylphosphonium) tetrachloridocobaltate(II), highlighting its coordination geometry.

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Cite This Study

Wang et al. (2026) studied this question.

synapsesocial.com/papers/6a895f62ca7ade938187dfa9 https://doi.org/10.1515/ncrs-2026-0305

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Crystal structure of bis(cyanomethyl-triphenylphosphonium) tetrachloridocobaltate(II), C 40 H 34 Cl 4 CoN 2 P 2

Key Points

Implication

Discussion

Cite This Study

Crystal structure of bis(cyanomethyl-triphenylphosphonium) tetrachloridocobaltate(II), C 40 H 34 Cl 4 CoN 2 P 2

Key Points

Implication

Discussion

Cite This Study

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