Dual Photoredox/Nickel-Catalyzed Atroposelective C–N Coupling with Carbazoles and Indoles as N -Nucleophiles

Key Points

• To develop an efficient method for atroposelective C–N coupling using carbazoles and indoles.
• Utilized dual photoredox and nickel-catalysis for the C–N coupling reaction
• Investigated various N-nucleophiles in the reaction
• Characterized the formed heterobiaryl atropisomers
• Successfully created heterobiaryl atropisomers with high atroposelectivity
• Demonstrated the versatility of carbazoles and indoles as N-nucleophiles
• Achieved effective C–N coupling at room temperature