Photoredox-catalyzed trifluoromethylation improves synthesis of heterocycles, suggesting new methods for complex compounds.
A photoredox-catalyzed trifluoromethylation/cyclization of N-allylbenzimidazoles using eosin Y-Na₂ under visible light affords trifluoromethylated benzimidazo-fused heterocycles. Two complementary protocols are established: Method A employs Togni's II under nitrogen-the first example of...
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Kuang et al. (2025) studied this question.
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