Unsaturated C 6 fatty acid methyl esters as reference molecules for biodiesel: kinetics of H-atom abstraction and addition

This study reports accurate thermal rate constants for H-abstraction and H-addition by atomic H in C 6 unsaturated FAMEs: methyl ( Z / E )-hex-2-, -3-, and -4-enoate, and methyl hex-5-enoate, providing a consistent kinetic dataset.