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Demonstrates a reversed-polarity approach to B-alkyl Suzuki reactions in organic synthesis, suggesting efficient alternatives.
A variety of trans -alkenyl-9-BBN derivatives have been prepared in situ and then coupled with alkyl bromides by utilizing palladium catalysis with the electron-rich and sterically encumbered tricyclohexylphosphine ligand.
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Siapkaras et al. (2026) studied this question.
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