Enhanced CO2 Binding Affinity of a High-Uptake rht-Type Metal−Organic Framework Decorated with Acylamide Groups

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Abstract

An rht-type metal-organic framework (MOF) prepared from M(2)(carboxylate)(4) (M = Cu, Co) paddlewheel clusters and a flexible C(3)-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO(2) uptake, an enhanced heat of adsorption, and higher selectivity toward CO(2)/N(2) in comparison with what was previously observed for an analogous MOF with alkyne groups.

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Zheng et al. (Tue,) studied this question.

synapsesocial.com/papers/6a00d0c9831589f3542decfb https://doi.org/https://doi.org/10.1021/ja110042b

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