Material Design Concept of Lithium‐Excess Electrode Materials with Rocksalt‐Related Structures for Rechargeable Non‐Aqueous Batteries

Dependence on lithium-ion batteries for automobile applications is rapidly increasing, and further improvement, especially for positive electrode materials, is indispensable to increase energy density of lithium-ion batteries. In the past several years, many new lithium-excess high-capacity electrode materials with rocksalt-related structures have been reported. These materials deliver high reversible capacity with cationic/anionic redox and percolative lithium migration in the oxide/oxyfluoride framework structures, and recent research progresses on these electrode materials are reviewed. Material design strategies for these lithium-excess electrode materials are also described. Future possibility of high-energy non-aqueous batteries with advanced positive electrode materials is discussed for more details.