Theoretical Study on the Co II /Co III and Co II /Co IV Catalytic Cycles in Co II (salen)-Catalyzed Radical Fluorination with Various Different NF-Type Fluorinating Reagents

Co II (salen)-catalyzed radical fluorination provides a mild and efficient approach for the construction of carbon-fluorine bonds. However, the mechanistic role of different NF-type fluorinating reagents and the corresponding catalytic cycle pathways...