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Experimental study demonstrates catalyst-free photoinduced C–C bond cleavage in arylamines under visible light, indicating a green pathway for selective chemical synthesis.
By introducing a polar atom at the γ-position of amine, the site-selective oxidative cleavage of the saturated C–C single bond in arylamines can be easily achieved by simple visible light irradiation with O₂ as a benign oxidant and catalyst free.
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Zhou et al. (2021) studied this question.
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