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A non-emissive dinuclear iridium(III) complex (SP-2) linked via an azo group has been adopted as a phosphorescent probe for sulphite and bisulphite. SP-2 exhibits a turn-on phosphorescent response toward sulphite and bisulphite with high selectivity and sensitivity. Furthermore, this probe can be used for living cell imaging to identify the presence of both external sulphite/bisulphite supplemented into cell cultures and endogenous sulphite/bisulphite biosynthesised in living cells.
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Li et al. (2013) studied this question.
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