Energy and Mass Coupling Efficiency Enhancement and Performance Optimization of an Integrated Liquid Air Energy Storage and SOEC-Based Green Ammonia Synthesis System

Addressing the challenges of fluctuating renewable energy integration and stable green ammonia production, this study develops and optimizes a deeply integrated system comprising Solid Oxide Electrolysis Cells (SOEC), Liquid Air Energy Storage (LAES), Air Separation Units (ASU), and Haber–Bosch (HB) synthesis. We constructed a simulation model in Aspen Plus incorporating Ru/C catalyst kinetic parameters to analyze key subsystem parameters and optimize operating conditions based on maximized economy and efficiency. At the integrated system level, a parametric analysis of ammonia condensation temperature was further conducted to investigate the coupling characteristics. Using real power output data from Inner Mongolia, we formulated a dynamic energy scheduling strategy satisfying 24-h self-balancing constraints. Results indicate that a system producing 1415 tons of ammonia per day achieves a maximum hourly integrated profit of 69,838 CNY under optimal conditions: a hydrogen-to-nitrogen ratio of 2.98:1, operating pressure of 169 bar, reactor inlet temperature of 380 °C, and ammonia condensation temperature of −9 °C. Increasing the LAES throttle valve outlet pressure from 1 bar to 9 bar improved round-trip efficiency from 52.65% to 72.18%. The integrated-level parametric analysis reveals that the specific electricity consumption per unit mass of ammonia exhibits a non-monotonic trend with a minimum of 8.67 kWh/kg at −10 °C, reflecting the trade-off between refrigeration power consumption and cold energy recovery. In dynamic scheduling scenarios, the system maintains a maximum constant load of 45.78 MW with a steady-state liquid ammonia output of 6543 kg/h. This work optimizes both economic performance and system stability, providing a significant reference for the large-scale development of green ammonia systems.