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We develop a coordinate-space model for dynamical correlations in an inhomogeneous electron gas. The model treats opposite-spin and same-spin pairs separately, and it also accounts properly for correlation contributions to the kinetic energy. Furthermore, it gives identically zero correlation energy in the case of one-electron systems. Applications to the uniform electron gas and to the atoms H through Ar are reported.
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Axel D. Becke
Dalhousie University
The Journal of Chemical Physics
Queen's University
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Axel D. Becke (Fri,) studied this question.
synapsesocial.com/papers/6a06bbf66b3d000707582ec2 — DOI: https://doi.org/10.1063/1.454274