Key points are not available for this paper at this time.
Formation of a carbon–palladium bond to the unsubstituted cyclopentadiene ring occurs during the cyclopalladation of 4-ferrocenyl-1,3-oxazolines and leads to a new type of metalated ferrocene (see scheme). These chiral complexes catalyze the asymmetric aza-Claisen rearrangement of allylic imidates.
Moyano et al. (Fri,) studied this question.