Synthesis of an amidinate-supported arsasilene and its attempted oxidation

Jicheng Wang; Yufen Yang; Zhicheng Xiao; Manbo Zhang; Bin Li

doi:10.1039/d6cc01524g

January 1, 2026Chemical Communications

Synthesis of an amidinate-supported arsasilene and its attempted oxidation

View Full Paper

Ask AI

Bookmark

Share

Key Points

The research aims to synthesize a bulky arsenide anion and a corresponding arsasilene through innovative chemical methods.
Developed synthesis method for the arsenide anion [As(SiiPr3)2]¯.
Synthesized arsasilene LSi(SiiPr3)=AsSiiPr3 using 1,2-silyl migration of the arsinosilylene.
Explored the oxidation process involving single-electron transformations.
Successful synthesis of the bulky arsenide anion [As(SiiPr3)2]¯ confirmed.
Arsasilene LSi(SiiPr3)=AsSiiPr3 was synthesized, showcasing its potential for further studies.
Oxidation attempts revealed insights into electron behavior in the synthesized compounds.

Implication

Synthesis investigates oxidation of a bulky arsenide anion in unique chemical compounds, suggesting novel pathways.

Abstract

The practical synthesis of the bulky arsenide anion, [As(SiiPr3)2]¯, was developed. Then a ylide-like arsasilene LSi(SiiPr3)=AsSiiPr3 (L = PhC(NtBu)2) (2) was synthesized via 1,2-silyl migration of the arsinosilylene LSi-As(SiiPr3)2. Single-electron...

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Wang et al. (2026) studied this question.

synapsesocial.com/papers/6a1689ce0c924ddd1bd58801 https://doi.org/10.1039/d6cc01524g

View Full Paper

Ask AI

Bookmark

Share

Synthesis of an amidinate-supported arsasilene and its attempted oxidation

Key Points

Implication

Abstract

Discussion

Cite This Study

Synthesis of an amidinate-supported arsasilene and its attempted oxidation

Key Points

Implication

Abstract

Discussion

Cite This Study

Keep reading

Keep reading