Bis-α,ω-bisacylphosphane Oxides: Simple Access to Crosslinked Polymers with Tunable Properties

Renata Raptova; Tanja Wiesner; Daniel Griess; Julian Maier; Roland C. Fischer; Anne-Marie Kelterer; Mercedes Linares‐Moreau; Christoph Walkner; Thomas Griesser; Mathias Wiech; Georg Gescheidt; Michael Haas

doi:10.1039/d6ta01719c

January 1, 2026Journal of Materials Chemistry AOpen Access

Bis-α,ω-bisacylphosphane Oxides: Simple Access to Crosslinked Polymers with Tunable Properties

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Key Points

To efficiently synthesize bis-α,ω-bisacylphosphine oxides and explore their properties.
Conducted one-pot synthesis of bis-α,ω-bisacylphosphine oxides by coupling α,ωdibromoalkanes with sodium bis(mesitoyl)-phosphide.
Characterized the resulting tetrafunctional photoinitiators.
The synthesized photoinitiators exhibited absorption characteristics similar to parent bisacylphosphine oxides.

Implication

Demonstrates tunable properties of crosslinked polymers from synthesized bisacylphosphine oxides, highlighting their versatility.

Abstract

We present an efficient one-pot synthesis of bis-α,ω-bisacylphosphine oxides (Bis-BAPOs) obtained by coupling α,ωdibromoalkanes with sodium bis(mesitoyl)-phosphide. The resulting tetrafunctional photoinitiators display absorption characteristics similar to the parent BAPO, yet...

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Cite This Study

Raptova et al. (2026) studied this question.

synapsesocial.com/papers/6a17ddab3fad632b0f9da667 https://doi.org/10.1039/d6ta01719c

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Bis-α,ω-bisacylphosphane Oxides: Simple Access to Crosslinked Polymers with Tunable Properties

Key Points

Implication

Abstract

Discussion

Cite This Study

Bis-α,ω-bisacylphosphane Oxides: Simple Access to Crosslinked Polymers with Tunable Properties

Key Points

Implication

Abstract

Discussion

Cite This Study

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