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Photochemical study reveals water-soluble red-shifted coumarin photocages activated by green light, indicating improved molecular tools for targeted light-triggered release.
Easily accessible green-light activatable (>500 nm) photocages based on red-shifted, π-extended coumarin scaffolds are developed with uncaging efficiencies similar to those of recently introduced BODIPY derivatives. The photocages possess increased aqueous solubility, high absorption coefficients within the 450-600 nm range, and exceptionally high two-photon cross sections.
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Bojtár et al. (2019) studied this question.
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