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January 1, 2026CrystEngComm

Crystal engineering of p -sulfocinnamic acid into mononuclear cationic Fe( ii ), Co( ii ) and Fe( iii ) complexes

Xiao-Chun Li Joanne Wong Mengmeng Wang Youssef Draoui Mariusz Wolff Koen Robeyns Aurelian Rotaru Yann Garcia

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Key Points

The research aims to explore the crystal engineering of mononuclear complexes using sulfocinnamic acid (Hpsca) as a ligand or counteranion.
Developed diverse crystal architectures using Hpsca to form mononuclear cationic complexes.
Stabilized complexes of iron (Fe) and cobalt (Co) in different oxidation states.
Successfully stabilized cationic mononuclear complexes with Fe(II), Co(II), and Fe(III) using Hpsca.
Diverse crystal structures were achieved, indicating flexible coordination of the ligand.

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Implication

Explores new crystal architectures using sulfocinnamic acid in metal complexes, suggesting novel properties.

Abstract

Diverse crystal architectures were stabilized with Hpsca − used as counteranion or ligand in mononuclear complexes.

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Cite This Study

Li et al. (2026) studied this question.

synapsesocial.com/papers/6a1bd1f65783ba022b6fd649 https://doi.org/10.1039/d6ce00068a

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