Reversible solid–gas chemical equilibrium between a 0-periodic deformable molecular tecton and a 3-periodic coordination architecture

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A reversible solid-gas chemical equilibrium can be established and structurally characterized between a 0-periodic deformable molecular tecton [Cu(L)2(H2O)] and a 3-periodic porous coordination architecture [Cu(L)2]n. Novelty: ClaimNovelty.INCREMENTAL. Consensus alignment: ConsensusAlignment.NEUTRAL.

Liu Deng; Mian Li; Dan Li

doi:10.1039/b911955h

January 1, 2009Chemical Communications

Reversible solid–gas chemical equilibrium between a 0-periodic deformable molecular tecton and a 3-periodic coordination architecture

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Abstract

The reversible crystal transformation between a hexagonal (R3[combining macron]) porous coordination architecture [Cu(L)(2)](n) (L = 3-(pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1,2,4-triazole), and a monoclinic (C2/c) molecular tecton [Cu(L)(2)(H(2)O)], was chemically implemented and structurally interpreted.

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Deng et al. (2009) studied this question.

synapsesocial.com/papers/6a1cd56443108573611dc133 https://doi.org/10.1039/b911955h

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Reversible solid–gas chemical equilibrium between a 0-periodic deformable molecular tecton and a 3-periodic coordination architecture

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Abstract

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Reversible solid–gas chemical equilibrium between a 0-periodic deformable molecular tecton and a 3-periodic coordination architecture

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