Visible Light-Induced Ipso-Chalcogenation of Aryl/Alkenyl Boronic Acids Assisted by a Chalcogen-Radical Transfer (ChRT) Strategy

Arup K. Kabi; Renu Chaudhary; Dulal Musib; Bartłomiej Sadowski

doi:10.1039/d6cc02407f

January 1, 2026Chemical Communications

Visible Light-Induced Ipso-Chalcogenation of Aryl/Alkenyl Boronic Acids Assisted by a Chalcogen-Radical Transfer (ChRT) Strategy

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Key Points

This research aims to develop a method for the ipso-chalcogenation of aryl and alkenyl boronic acids using visible light without transition metals.
Transition-metal free approach
Employs visible light for activation
Applicable to various electronically-diverse aromatic boronic acids
Achieved successful ipso-chalcogenation of multiple aryl boronic acids under mild conditions.
Demonstrated functionalization versatility across different electronic variations of boronic acids.

Implication

Demonstrates ipso-chalcogenation in aryl boronic acids, suggesting a new functionalization method.

Abstract

Herein, we report a transition-metal free, visible light-induced method for the ipso-chalcogenation of aryl/alkenyl boronic acids. Our approach enables functionalization of a variety of electronically-diverse aromatic boronic acids under mild...

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Cite This Study

Kabi et al. (2026) studied this question.

synapsesocial.com/papers/6a2117fdd499ed480b170d07 https://doi.org/10.1039/d6cc02407f

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Visible Light-Induced Ipso-Chalcogenation of Aryl/Alkenyl Boronic Acids Assisted by a Chalcogen-Radical Transfer (ChRT) Strategy

Key Points

Implication

Abstract

Discussion

Cite This Study

Visible Light-Induced Ipso-Chalcogenation of Aryl/Alkenyl Boronic Acids Assisted by a Chalcogen-Radical Transfer (ChRT) Strategy

Key Points

Implication

Abstract

Discussion

Cite This Study

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