Key points are not available for this paper at this time.
Nanosized palladium colloids, generated in situ by reduction of Pd(II) to Pd(0) Eq. (a), are involved in the catalysis of phosphane-free Heck and Suzuki reactions with simple palladium salts such as PdCl(2) or Pd(OAc)(2), as demonstrated by transmission electron microscopic investigations.
Reetz et al. (Mon,) studied this question.