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Abstract Reported here is an efficient and simple ether‐directed iridium‐catalyzed enantioselective C( sp 3 )−H borylation of cyclopropanes. Various functional groups were well‐tolerated, affording a vast array of chiral cyclopropanes with high enantioselectivities. We also demonstrated that the turnover numbers of the current reaction could be up to 335.
Xie et al. (Fri,) studied this question.