Tuning the Tetraarylcyclopentadienones from iron tricarbonyl complexes: effects in Transfer Hydrogenation and solubility

Esteban Zingales; Miguel  Angel Huertos; Carlos Sanchez-Cano

doi:10.1039/d6dt00706f

January 1, 2026Dalton TransactionsOpen Access

Tuning the Tetraarylcyclopentadienones from iron tricarbonyl complexes: effects in Transfer Hydrogenation and solubility

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Key Points

The study aims to determine how different ligands in iron tricarbonyl complexes influence transfer hydrogenation efficiency and solubility.
Examined various coordinated ligands in cyclopentadienone iron tricarbonyl complexes.
Analyzed H transfer mechanisms during transfer hydrogenation catalysis.
Assessed solubility characteristics of the resulting complexes.
Specific ligands enhanced transfer hydrogenation rates significantly, indicating potential for optimized catalysts.
Increased solubility was observed with particular ligand modifications, facilitating easier handling in reactions.

Implication

Investigates how ligand nature affects transfer hydrogenation in catalysts, suggesting optimization pathways.

Abstract

The nature of the ligands coordinated to the metal in cyclopentadienone iron tricarbonyl (CIC) complexes is important for the activation or H transfer steps of Transfer Hydrogenation (TH) catalysis. Previous...

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Cite This Study

Zingales et al. (2026) studied this question.

synapsesocial.com/papers/6a2cf5aefaef96ed7f057aa6 https://doi.org/10.1039/d6dt00706f

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Tuning the Tetraarylcyclopentadienones from iron tricarbonyl complexes: effects in Transfer Hydrogenation and solubility

Key Points

Implication

Abstract

Discussion

Cite This Study

Tuning the Tetraarylcyclopentadienones from iron tricarbonyl complexes: effects in Transfer Hydrogenation and solubility

Key Points

Implication

Abstract

Discussion

Cite This Study

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