A bridging thiocarbyne ligand in diiron(I) complexes enables unconventional isomerization pathways and structural diversity leading to potent cytotoxicity

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This is a Experimental Study study.

Lorenzo Biancalana; Ekatarina Mihajlović; Gianluca Ciancaleoni; Marija Mojić; Sanja Jelača; Stefano Zacchini; Guido Pampaloni; Biljana Dojčinović; Danijela Maksimović‐Ivanić; Sanja Mijatović; Fabio Marchetti

doi:10.1039/d5qi01498k

January 1, 2025Inorganic Chemistry Frontiers

A bridging thiocarbyne ligand in diiron(I) complexes enables unconventional isomerization pathways and structural diversity leading to potent cytotoxicity

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Key Points

The bridging thiocarbyne ligand facilitates novel isomerization pathways, enhancing cytotoxicity potential.
Eight diiron(I) complexes were synthesized, featuring a unique bridging methylthiocarbyne ligand.
This study highlights the structural diversity achieved through the substitution of carbonyls in the complexes.
Unconventional isomerization pathways may lead to innovative applications in cytotoxic agents.

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Implication

Synthesis of diiron(I) complexes with thiocarbyne ligands shows structural diversity, suggesting new isomerization pathways.

Abstract

Eight diiron(I) bis-cyclopentadienyl complexes with a bridging methylthiocarbyne ligand were prepared from the tris-carbonyl precursor [Fe2Cp2(CO)2(μ-CO)(μ-CSMe)]CF3SO3 (Cp = η5-C5H5) through the substitution of one or two terminal carbonyls with a...

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Biancalana et al. (2025) studied this question.

synapsesocial.com/papers/68d9051b41e1c178a14f4cb2 https://doi.org/10.1039/d5qi01498k

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A bridging thiocarbyne ligand in diiron(I) complexes enables unconventional isomerization pathways and structural diversity leading to potent cytotoxicity

Key Points

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Implication

Abstract

Discussion

Cite This Study

A bridging thiocarbyne ligand in diiron(I) complexes enables unconventional isomerization pathways and structural diversity leading to potent cytotoxicity

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

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