The deuteration of water produces the conformational change shown in the figure in the anisole⋅⋅⋅water complex. The value of the θ angle decreases from 138 to 128°, and the secondary interaction O⋅⋅⋅HMe is replaced by O⋅⋅⋅HPh. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z461860_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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Giuliano et al. (2004) studied this question.
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