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Demonstrates self-assembly of metal-organic frameworks using capillary and van der Waals attractions, revealing crystal orientation control.
MOFs get attraction: Supraparticle self-assembly of a colloidal metal–organic framework (MOF) is achieved through simple capillary and van der Waals attractions. When suspensions of MOF particles are allowed to evaporate, hexagonal packings with controlled crystal orientation result (see scheme). The self-assembly can be visualized at the single-particle level. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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Yanai et al. (2012) studied this question.
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