Engineering Synergistic Di-Iron Sites and Anion Microenvironments in a Metal-Organic Framework Catalyst for Aerobic Wacker-Type Olefin Oxidation

Li J; Fu‐Qi Mi; Teng Zhang

doi:10.1039/d6cy00630b

January 1, 2026Catalysis Science & Technology

Engineering Synergistic Di-Iron Sites and Anion Microenvironments in a Metal-Organic Framework Catalyst for Aerobic Wacker-Type Olefin Oxidation

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Key Points

The aim is to enhance catalytic performance by precisely engineering metal-metal synergy and local anion environments in metal-organic frameworks.
Constructed cooperative multinuclear metal sites within metal-organic frameworks.
Controlled local anion microenvironments.
Evaluated catalytic performance in aerobic Wacker-type olefin oxidation.
Achieved significant improvement in catalytic performance compared to traditional catalysts.
Demonstrated precise control over metal-metal synergy and anion environments.
Validated effectiveness with multiple olefin substrates.

Implication

Demonstrates enhanced catalytic performance in metal-organic frameworks, indicating improved synergy and site control.

Abstract

The deliberate construction of cooperative multinuclear metal sites within heterogeneous catalysts offers a promising strategy for enhancing catalytic performance, yet precise control over metal-metal synergy and local anion environments remains...

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Cite This Study

J et al. (2026) studied this question.

synapsesocial.com/papers/6a323d23d50b63ecad206f78 https://doi.org/10.1039/d6cy00630b

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Engineering Synergistic Di-Iron Sites and Anion Microenvironments in a Metal-Organic Framework Catalyst for Aerobic Wacker-Type Olefin Oxidation

Key Points

Implication

Abstract

Discussion

Cite This Study

Engineering Synergistic Di-Iron Sites and Anion Microenvironments in a Metal-Organic Framework Catalyst for Aerobic Wacker-Type Olefin Oxidation

Key Points

Implication

Abstract

Discussion

Cite This Study

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