This review demonstrates various reactions involving transition metal organometallics for synthetic applications, indicating their utility in organic synthesis.
Reactivity of co-ordinated ligands isomerization and rearrangement reactions epoxidation of alkenes oxidation of alkenes co-ordination of alkenes co-ordinated alkenes and alkynes as synthetic intermediates pi-allyl complexes of palladium as synthetic intermediates further applications of hydrocarbon pi complexes as synthetic intermediates delta bound complexes as nucleophiles carbonyl insertion further insertion and coupling reactions carbene complexes organometallic methods for protection, stabilization and masking in organic synthesis organometallic strategies in natural product synthesis uses of transition metals in the synthesis of heterocycles.
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