A Review on Polymer-Modified Cementitious Materials for Underwater Repair: Workability, Bonding, Mechanical Performance and Durability

Underwater concrete infrastructure is gradually damaged by water scouring, chloride ingress, freeze–thaw cycles, and fatigue loading, so reliable in situ repair materials are increasingly needed. Conventional cement-based repair materials are often unsuitable for underwater use because they disperse in water, bond weakly to wet substrates, and show limited durability. Polymer-modified cementitious materials can reduce these problems by combining cement compatibility with polymer film formation and interfacial strengthening. Water-soluble polymers mainly improve fresh-state cohesion and anti-washout performance through adsorption, bridging, and flocculation regulation. In comparison, polymer emulsions and latexes are more effective after hardening, improving bonding, crack resistance, and durability through polymer films and organic–inorganic networks. For self-leveling underwater repair, the flow spread should reach at least 130 mm. For vertical repair with a 20 mm layer, a yield stress of about 360 Pa is needed to prevent sagging. Therefore, performance should not be judged by strength alone, but by constructability, interfacial water films, and pore connectivity. Future studies should consider responsive polymers, multi-component modification, standardized tests, and low-carbon binders.