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July 13, 2026Journal of Coordination Chemistry

Octahedral Cu(II) perchlorate complexes of n-methyl-2-pyridones

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Authors

DDDiane A. DickieUniversity of VirginiaMTMark M. TurnbullClark University

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Implication

Randomized trial explores the structural properties of copper complexes, suggesting significant Jahn-Teller distortions.

Key Points

  • The study investigates the formation and structural characteristics of copper(II) perchlorate complexes with n-methyl-2-pyridones.
  • Synthesis of copper(II) perchlorate complexes through reaction with n-methyl-2-hydroxypyridine.
  • Variable temperature X-ray structural analysis to assess distortions in copper complexes.
  • Complexes were successfully synthesized, including variants with different methyl substitutions.
  • Structural analysis showed Jahn-Teller distortions varying between elongation and compression.
  • Compound 1 exhibited a phase transition depending on temperature from elongated to compressed structure.

Cite This Study

Dickie et al. (2026) studied this question.

synapsesocial.com/papers/6a54807d475c38bf615a552ehttps://doi.org/10.1080/00958972.2026.2695830
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