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Adsorption of carbon dioxide near its critical point on DeGussa IV activated carbon is investigated in this study. A volumetric method was used to measure the adsorption/desorption isotherms at 284, 300, 305, 310, and 314 K over a large pressure range. At subcritical temperatures, adsorption isotherms display a discontinuity at the vapor pressure of carbon dioxide, and desorption hysteresis is observed. However, there is no desorption hysteresis if adsorption is terminated before vapor−liquid transition occurs. At supercritical temperatures, adsorption isotherms display a plateau, and the excess decreases beyond the critical pressure. No hysteresis occurs during the desorption process. The adsorption isotherms can be represented very well by the simplified local density model.
Chen et al. (Tue,) studied this question.