Rhodium(I)‐Catalyzed 1,4‐Silicon Shift of Unactivated Silanes from Aryl to Alkyl: Enantioselective Synthesis of Indanol Derivatives

Let's swap! Highly reactive alkyl rhodium species undergo facile CSi bond activation resulting in an overall 1,4-Si/Rh positional switch. This reactivity is utilized to access densely functionalized indanol derivatives in a highly enantioselective manner (see scheme). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.