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September 5, 2008Synthesis

Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage

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To review modern developments in selective and efficient transition-metal-catalyzed carbon-carbon bond formation via direct activation of unreactive carbon-hydrogen bonds.
Surveyed published literature focusing on transition-metal-mediated catalytic activation of inert C-H bonds.
Analyzed mechanistic strategies and catalyst systems used to facilitate direct C-C bond construction.
Transition-metal catalysts successfully mediate direct C-C bond coupling without the need for pre-functionalized reaction partners.
Reported methodologies demonstrate high chemical efficiency and regioselectivity across diverse unreactive C-H substrate classes.

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Implication

Review demonstrates advances in transition-metal-catalyzed carbon-carbon coupling via carbon-hydrogen bond cleavage, highlighting streamlined synthetic pathways for complex organic molecules.

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Kakiuchi et al. (2008) studied this question.

synapsesocial.com/papers/6a6f253d78a11c550e08d200 https://doi.org/10.1055/s-2008-1067256

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Implication

Review demonstrates advances in transition-metal-catalyzed carbon-carbon coupling via carbon-hydrogen bond cleavage, highlighting streamlined synthetic pathways for complex organic molecules.

Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage

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Implication

Cite This Study

Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage

Key Points

Discussion

Implication

Cite This Study

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