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Explores photophysical properties of zigzag-type molecular belts with enhanced chiroptical features.
Asymmetric synthesis of enantioenriched zigzag-type molecular belts featuring copper/H 8 -binaphthol-catalyzed kinetic resolution of a resorcinarene derivative and subsequent transformations was developed. The acquired rigid and C 4 -symmetric belt exhibited remarkably enhanced photophysical and chiroptical properties in comparison to its conformationally fluxional macrocyclic precursor.
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Mao et al. (2023) studied this question.
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