Flexible synthesis generates 2-deoxy C-disaccharides in high selectivity, indicating efficiency in glycoside formation.
Link! Two, three, four! A rapid and flexible synthesis of native (1→n)-linked C-disaccharides (n=2, 3, 4; left) is possible. The configuration of the pseudoanomeric carbon was readily established by an epoxidation/ring-opening sequence. The synthesis of (1→n)-linked 2-deoxy-C-disaccharides (right) with high diastereoselectivity follows an even shorter route.
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Koester et al. (2013) studied this question.
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