Microstructure and Tribological Characterization of Coated PEEK-Based Polymers

This study investigates the tribological performance of chromium nitride (CrN)-coated polyether ether ketone (PEEK) polymers. CrN coating was deposited by physical vapor deposition (PVD) onto two commercially available substrates: neat PEEK and a modified PEEK. The suitability of the coated substrates for tribological applications was evaluated using ball-on-disc tests against stainless-steel (SS) counterparts. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) confirmed the high thermal stability of the PEEK substrates, ensuring compatibility with low-temperature coating deposition. Microstructural analysis revealed dense and continuous CrN coatings with an average thickness of ~1.5 µm on both substrates. Tribological results of selected PEEK-based polymers showed that under the applied load of 2 N, uncoated PEEK substrates exhibited lower coefficients of friction (COFs) and smoother wear tracks compared with coated samples. In contrast, under the applied load of 4 N, CrN-coated PEEK substrates demonstrated reduced friction and improved stability relative to uncoated PEEK. This behavior is attributed to load-induced tribo-oxidation and the formation of a chromium-oxide-rich tribolayer that stabilized the sliding interface and suppressed adhesive wear. Overall, the results demonstrate that CrN coatings significantly enhance the load-bearing capacity and tribological performance of selected PEEK substrates under applied load of 4 N, highlighting their potential for advanced lightweight engineering applications requiring improved wear resistance.