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The ternary phase diagram for the pseudoternary compound LixCuyMo6S8 at room temperature has been determined using in situ X-ray diffraction and measurements of the voltage V of Li/LixCuyMo6S8 electrochemical cells. The coexistence curves versus chemical potential of Cu and Li have also been determined. The behaviour of V(x) and ( delta x/ delta V)y is compared with that calculated using the Bragg-Williams approximation. The authors also discuss general features of ternary phase diagrams in intercalation compounds, stressing how important it is to know the entire ternary diagram when the host contains two mobile guests.
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McKinnon et al. (1985) studied this question.
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