Synthesis and characterization of BODIPY dyads reveals charge transfer behavior in excited states, suggesting new optical applications.
We report the synthesis and characterization of symmetric BODIPY dyads where the chromophores are attached at the meso position, using either a phenylene bridge or direct linkage. Both molecules undergo symmetry-breaking intramolecular charge transfer in the excited state, and the directly linked dyad serves as a visible-light-absorbing analogue of 9,9'-bianthryl.
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Whited et al. (2011) studied this question.
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