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In this work, a heteroatom-containing luminogen (TPE-Py) with multi-functionalities was synthesized in a reasonable yield by melding a pyridinium unit with tetraphenylethene through vinyl functionality. TPE-Py is weakly emissive in solution but becomes a strong emitter when aggregated as nanoparticle suspensions in poor solvents or in the solid state, displaying a phenomenon of aggregation-induced emission. Crystallization generally weakens and red-shifts the light emission. The crystalline aggregates of TPE-Py, however, emit stronger and bluer light than their amorphous counterparts. The solid-state emission of TPE-Py can be reversibly switched between green and yellow color by grinding–fuming and grinding–heating processes with a high contrast due to the transformation from the crystalline to the amorphous state and vice versa. The large Stokes shift and well-ordered molecular arrangement of the crystalline microrods of TPE-Py make it promising as an optical waveguide material with a low optical loss coefficient of ∼0.032 dB μm−1. TPE-Py works as a good fluorescent visualizer for specific staining of mitochondria in living cells with a high photostability, thanks to its hydrophobic and cationic features.
Zhao et al. (Tue,) studied this question.