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Novel solvent systems reveal how lignin solubility varies with different eutectic molecular liquids, highlighting their potential for valorization.
Lignin dissolution is of great importance for the valorization of lignin, and development of novel efficient solvent systems is a crucial topic. Herein, 17 kinds of 1,5-diazabicyclo[5.4.0]-5-undecene-based eutectic molecular liquids (EMLs) were designed for dissolution of industrial lignins. The solubility of lignin in the EMLs significantly depended on the types of the EMLs and lignin. Also the relationship between lignin solubility and the solvatochromic parameters (α, β, and π*) varied significantly based on the EMLs and the types of lignin.
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Liu et al. (2019) studied this question.
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