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The unsymmetrically substituted magnesium alkyl Mg(Bun){CH[SPh][SiPh2(CH 2NC5H10)]} (NC5H10 = 1-piperidyl) with a stereogenic metalated carbon atom is obtained by deprotonation of an (aminomethyl)[(phenylthio)methyl]silane with MgBunBus and examined by single crystal X-ray diffraction analysis and theoretical methods.
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Strohmann et al. (2000) studied this question.
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